Ruthenium(II) complexes with pyridine-based Schiff base ligands: Synthesis, structural characterization and catalytic hydrogenation of ketones

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dc.contributor.authorBuldurun, Kenan
dc.contributor.authorOzdemir, Metin
dc.date.accessioned2021-04-10T16:37:19Z
dc.date.available2021-04-10T16:37:19Z
dc.date.issued2020
dc.departmentMAUNen_US
dc.descriptionBULDURUN, Kenan/0000-0002-2462-7006en_US
dc.description.abstractThis study investigated the synthesis and characterization of which the result of the reaction of Schiff base ligands containing pyridine with [RuCl2(p-cymene)](2). The spectroscopic techniques used for the characterization process were the elemental analysis, mass spectroscopy, FT-IR, UV-Vis and H-1 and C-13 NMR. The results showed that Ru(II) complexes occured through the coordination of azomethine N, carbonyl and hydroxyl O atoms of the ligands. Ru(II) complexes were utilized as catalysts for the transfer hydrogenation of a series of ketones in the i-propanol solution and in the presence of KOH. The catalytic reactions indicated that the Ru(II) complexes (1a-d) were effective catalysts in the transfer hydrogenation reaction. (C) 2019 Elsevier B.V. All rights reserved.en_US
dc.description.sponsorshipScientific Research-Publications and Projects Research and Practice Center (BAYPUAM) [BAP-18-TBMY-4902-01]en_US
dc.description.sponsorshipThank Scientific Research-Publications and Projects Research and Practice Center (BAYPUAM) under research project no BAP-18-TBMY-4902-01 for their support.en_US
dc.identifier.doi10.1016/j.molstruc.2019.127266
dc.identifier.issn0022-2860
dc.identifier.issn1872-8014
dc.identifier.scopus2-s2.0-85074048755
dc.identifier.scopusqualityQ1
dc.identifier.urihttps://doi.org/10.1016/j.molstruc.2019.127266
dc.identifier.urihttps://hdl.handle.net/20.500.12639/2257
dc.identifier.volume1202en_US
dc.identifier.wosWOS:000501486700079
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevieren_US
dc.relation.ispartofJournal Of Molecular Structureen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectSchiff baseen_US
dc.subjectSpectroscopic techniquesen_US
dc.subjectCatalysisen_US
dc.subjectRu(II) complexesen_US
dc.subjectTransfer hydrogenationen_US
dc.titleRuthenium(II) complexes with pyridine-based Schiff base ligands: Synthesis, structural characterization and catalytic hydrogenation of ketonesen_US
dc.typeArticle

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