Electrophilic amination of diarylcadmium reagents: the effect of aminating reagent's structure

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dc.authorscopusid6505928976
dc.authorscopusid57199499217
dc.authorwosidkorkmaz, adem/AAM-5428-2021
dc.contributor.authorDaşkapan, Tahir
dc.contributor.authorKorkmaz, Adem
dc.date.accessioned2023-01-10T21:23:32Z
dc.date.available2023-01-10T21:23:32Z
dc.date.issued2022
dc.departmentFakülteler, Sağlık Bilimleri Fakültesi, İş Sağlığı ve Güvenliği Bölümüen_US
dc.description.abstractThe first and only work on the electrophilic amination of diarylcadmium reagents was published by our group. Herein we give the detailed results on this subject. We prepared 12 oximes and reacted them with diarylcadmiums as aminating agents to observe the effect of oxime's structure on the amination reaction. The results showed that the success of electrophilic amination of diarylcadmium reagents with oxime sulfonates is strongly influenced by the structure of the oxime. Based on the results of our research, we decided that O-substituted acetone oxime derivatives containing a suitable leaving group are the most suitable amination reagents for the high yield of amine.en_US
dc.description.sponsorshipAnkara University Research Foundation [15L0430009]; Turkish Higher Education Council (OYP Program)en_US
dc.description.sponsorshipThe authors greatly acknowledge financial support from Ankara University Research Foundation (grant no. 15L0430009) and The Turkish Higher Education Council (OYP Program).en_US
dc.identifier.doi10.1007/s12039-022-02106-5
dc.identifier.issn0974-3626
dc.identifier.issn0973-7103
dc.identifier.issue4en_US
dc.identifier.orcid0000-0002-0345-5794
dc.identifier.scopus2-s2.0-85142532195
dc.identifier.scopusqualityQ3
dc.identifier.urihttps://doi.org/10.1007/s12039-022-02106-5
dc.identifier.urihttps://hdl.handle.net/20.500.12639/4974
dc.identifier.volume134en_US
dc.identifier.wosWOS:000887916200001
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorKorkmaz, Adem
dc.language.isoen
dc.publisherIndian Acad Sciencesen_US
dc.relation.ispartofJournal of Chemical Sciencesen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAminationen_US
dc.subjectOrganocadmiumen_US
dc.subjectAminesen_US
dc.subjectOximesen_US
dc.subjectBenzamidesen_US
dc.subjectPrimary Aminesen_US
dc.subjectOrganozinc Reagentsen_US
dc.subjectGrignard-Reagentsen_US
dc.subjectOrganomagnesiumen_US
dc.subjectCopperen_US
dc.subjectCadmationen_US
dc.subjectZincen_US
dc.titleElectrophilic amination of diarylcadmium reagents: the effect of aminating reagent's structureen_US
dc.typeArticle

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