A Short and Efficient Asymmetric Synthesis of (+/-)-epi-Cytoxazone from cis-(1R,2S,5R)-Menthyl 4-Methoxyphenylglycidates

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dc.contributor.authorEr, Mustafa
dc.contributor.authorCoşkun, Necdet
dc.date.accessioned2020-01-29T18:52:07Z
dc.date.available2020-01-29T18:52:07Z
dc.date.issued2014
dc.departmentFakülteler, Fen-Edebiyat Fakültesi, Kimya Bölümüen_US
dc.description.abstractThe racemic epi-cytoxazone was synthesized, starting from p-anisaldehyde, in five steps and 48% overall yield. An efficient synthesis of azido alcohols has been achieved by regioselective ring opening of glycidates using NaN3 in MeOH-H2O. The key step of the process is reductive cyclization of azide carbonates by Zn-TMSCl.en_US
dc.description.sponsorshipUludap University Research FundUludag University [2001-2]en_US
dc.description.sponsorshipThe Uludap University Research Fund is gratefully acknowledged for its financial support (Project No 2001-2).en_US
dc.identifier.doi10.1007/s10600-014-1161-z
dc.identifier.endpage1074en_US
dc.identifier.issn0009-3130
dc.identifier.issn1573-8388
dc.identifier.issue6en_US
dc.identifier.scopus2-s2.0-84922105242
dc.identifier.scopusqualityN/A
dc.identifier.startpage1071en_US
dc.identifier.urihttps://dx.doi.org/10.1007/s10600-014-1161-z
dc.identifier.urihttps://hdl.handle.net/20.500.12639/901
dc.identifier.volume50en_US
dc.identifier.wosWOS:000345771400023
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherSPRINGERen_US
dc.relation.ispartofCHEMISTRY OF NATURAL COMPOUNDSen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subject(+/-)-epi-cytoxazoneen_US
dc.subject4-methoxyphenylglycidateen_US
dc.subjectZn-TMSCl reductionen_US
dc.subjectDarzen epoxidationen_US
dc.subjectazidesen_US
dc.titleA Short and Efficient Asymmetric Synthesis of (+/-)-epi-Cytoxazone from cis-(1R,2S,5R)-Menthyl 4-Methoxyphenylglycidatesen_US
dc.typeArticle

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